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Comptes Rendus Chimie
Sous presse. Epreuves corrigées par l'auteur. Disponible en ligne depuis le vendredi 15 juin 2012
Doi : 10.1016/j.crci.2012.05.002
Received : 20 Mars 2012 ;  accepted : 2 May 2012
Electrodeposited copolymer electrolyte into nanostructured titania electrodes for 3D Li-ion microbatteries
 

Nana Amponsah Kyeremateng a, b, Frederic Dumur c, Philippe Knauth b, Brigitte Pecquenard d, Thierry Djenizian a,
a LP3 Laboratory (UMR 7341), Chemistry of Materials Research Group, University of Aix-Marseille, Parc Scientifique et Technologique de Luminy, 13288 Marseille cedex 9, France 
b University of Aix-Marseille, Madirel (ELMA) UMR 7246, centre Saint-Jérôme, 13397 Marseille cedex 20, France 
c ICR (CROPS) UMR 7273, University of Aix-Marseille, centre Saint-Jérôme, 13397 Marseille cedex 20, France 
d Université de Bordeaux, CNRS, ICMCB, site ENSCPB, 87, avenue du Dr.-Schweitzer, 33608 Pessac, France 

Corresponding author.
Abstract

The electrochemical synthesis of a copolymer electrolyte (PEO-PMMA) into titania nanotubes is described and studied. Compared with the electrochemical systems based on solid electrolytes deposited by top-down techniques, the copolymer/titania nanotube material reveals high electrochemical performance, opening new perspectives for the fabrication of 3D all-solid-state microbatteries.


Keywords : Titania nanotubes, Nano-architectured electrodes, Electropolymerization, Copolymer electrolyte, All-solid-state microbatteries




© 2012  Published by Elsevier Masson SAS de la part de Académie des sciences.
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