The first trinuclear manganese triplesalen complex: Synthesis, structural, and magnetic characterization of
- 14/02/08
, Maik Heidemeier a, Roland Fröhlich b| pages | 8 |
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Abstract |
The reaction of the nitro-substituted triplesalen ligand with Mn(ClO4)2·6H2O in CH3CN in the presence of Et3N and DMSO results in the formation of
(1) which has been characterized by elemental analysis, FTIR, UV-vis-NIR, ESI-MS, single-crystal X-ray diffraction, and magnetic measurements. The triplesalen ligand
provides three salen-like coordination environments bridged in a meta-phenylene arrangement by a phloroglucinol backbone. The coordination environment of each MnIII ion is completed by two O-bonded DMSO molecules. The folding of the triplesalen ligand results in an overall dish-like geometry for the trication in 1. The magnetic characterization has been performed by temperature dependent magnetic susceptibility measurements and variable temperature-variable field (VTVH) magnetization data in order to determine both the exchange couplings J between the Si=2 ion and the local zero-field splittings Di. Simulations to the appropriate spin-Hamiltonian using a full-matrix diagonalization approach provided a weak antiferromagnetic interaction J=-0.30±0.05cm-1 but a strong magnetic anisotropy expressed by D=-4.0±0.4cm-1. The potential applications of 1 and forthcoming members of this new family of trinuclear manganese triplesalen complexes in molecule-based magnetism and homogenous catalysis are discussed.
Keywords : Polynuclear transition metal complexes, Manganese, Magnetic properties, Ligand folding, ESI-MS, FTIR
Plan
Vol 10 - N° 1-2
P. 71-78 - janvier-février 2007 Retour au numéroBienvenue sur EM-consulte, la référence des professionnels de santé.
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