Intrinsic vs. extrinsic inelastic scattering contributions in κ-(BEDT-TTF)2Cu[N(CN)2]Br - Transport measurements under hydrostatic pressure - 14/02/08
, Cemil Akinci a, Volodymyr Paschenko a, Bernd Wolf a, Eckart Uhrig a, Wolf Assmus a, Jürgen Schreuer b, Leonore Wiehl b, John Schlueter c, Jochen Wosnitza d, Dieter Schweitzer e, Michael Lang a| pages | 5 |
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Abstract |
Interlayer-resistivity measurements have been performed on a variety of single crystals of the quasi-two-dimensional organic superconductor
-(BEDT-TTF)2Cu[N(CN)2]Br. These crystals, which have been synthesized along two somewhat different routes, reveal strongly sample-dependent resistivity profiles: while the majority of samples shows a more or less pronounced
(T) maximum around 90K with a semiconducting behaviour above, some crystals remain metallic at all temperatures T≤300K. In the absence of significant differences in the crystals' structural parameters and chemical compositions, as proved by high-resolution X-ray and electron-probe-microanalysis [C. Strack et al., Phys. Rev. B 72 (2005) 054511], these results indicate that real structure phenomena, i.e. disorder and/or defects, may strongly affect the inelastic scattering. Comparative resistivity measurements under He-gas pressure on two crystals with strongly differing
(T) profiles indicate that these additional, sample-dependent scattering contributions are characterized by an extraordinarily strong pressure response which is highly non-monotonous as a function of temperature. No correlations have been found between the strength of these scattering contributions and other characteristic properties such as the glass transition at Tg=77K, the temperature T
40K, where the temperature dependence of the resistivity changes rather abruptly, or the superconducting transition temperature Tc.
Keywords : Electrical conduction, Organic compounds, Organic superconductors
Plan
Vol 10 - N° 1-2
P. 96-100 - janvier-février 2007 Retour au numéroBienvenue sur EM-consulte, la référence des professionnels de santé.
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