A practical and highly efficient transfer hydrogenation of aryl azides using a [Ru(p-cymene)Cl2]2 catalyst and sodium borohydride - 17/09/18
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Abstract |
Various aniline derivatives were synthesized by selective reduction of aryl azides in the presence of a dichloro(p-cymene)ruthenium(II) dimer ([Ru(p-cymene)Cl2]2) via hydrolysis of sodium borohydride. The hydrogenation reactions were carried out in aqueous media at room temperature. Most of the reactions were completed within 10 min with quantitative yields.
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Keywords : [Ru(p-cymene)Cl2]2, Homogeneous catalyst, Transfer hydrogenation, Aryl azide
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Vol 21 - N° 9
P. 880-883 - settembre 2018 Ritorno al numero
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