Preparation, characterization and catalytic activity of a nano-Co(II)-catalyst as a high efficient heterogeneous catalyst for the selective oxidation of ethylbenzene, cyclohexene, and benzyl alcohol - 03/10/13
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Abstract |
This paper reports the preparation of a nano-Co(II)-catalyst (NCC) by anchoring of Co ions on immobilized bipyridylketone over the nano-sized SiO2/Al2O3 mixed oxides. The nano-Co(II)-catalyst has been characterized by elemental analysis, BET, FT-IR, DR UV–vis and SEM. The catalytic activity of the catalyst towards the oxidation of ethylbenzene, cyclohexene, and benzylalcohol to different chemically and pharmaceutically important products were evaluated with tert-butyl hydroperoxide (TBHP) in the absence of solvent. Under optimized conditions, the nano-catalyst proved highly selective towards the acetophenone, 2-cyclohexene-1-one and benzaldehyde as reaction products, with excellent conversion rates.
Il testo completo di questo articolo è disponibile in PDF.Keywords : Co nano-catalyst, Oxidation, Ethylbenzene, Cyclohexene, Benzylalcohol, Aetophenone, 2-cyclohexene-1-one, Benzaldehyde
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Vol 16 - N° 10
P. 888-896 - ottobre 2013 Ritorno al numero
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